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Communication | Regular issue | Vol 4, No. 6, 1976, pp.1065-1072
Published online, 1st January, 1970
DOI: 10.3987/R-1976-06-1065
Synthesis of a Cyrokinin Metabolite

James D. McChesney* and Russell Buchman

*Department of Medicinal Chemistry, University of Kansas, 4070 Malott Hall, Lawrence, Kansas 66045-2506, U.S.A.

Abstract

A number of plant tissues convert approximately 20-25% of the cytokinin, 6-benzylaminopurine, into a stable, long-lived derivative previously identified tentatively as 7-glucofuranosyl-6-benzylaminopurine. This substance has been synthesized by an unambiguous route and shown not to be identical with the long-lived metabolite. Synthesis and comparison of 7-β-glucopyranosyl-6-benzylaminopurine with the metabolite proves that to be the structure of the metabolite instead.