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Communication | Regular issue | Vol 9, No. 10, 1978, pp.1409-1412
Published online, 1st January, 1970
DOI: 10.3987/R-1978-10-1409
The Structures of Ovatine, Lindheimerine, and Garryfoline, C20-Diterpenoid Alkaloids of Garrya ovata var. lindheimeri Torr.

S. William Pelletier,* Naresh V. Mody, and David S. Seigler

*Department of Chemistry, Institute for Natural Products Research, The University of Georgia, Chemistry Building, Athens, Georgia 30602-2556, U.S.A.

Abstract

Chemical investigation of alkaloids from Garrya ovata var. lindheimeri Torr. has led to the isolation and characterization of two new C20-diterpenoid alkaloids, ovatine (1) and lindheimerine (2), as well as the alkaloid garryfoline (3). Ovatine and garryfoline each exists as a mixture of C(20)-epimers; these alkaloids were chemically interconverted in high yield.