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Report | Regular issue | Vol 16, No. 11, 1981, pp.1963-1974
Published online, 1st January, 1970
DOI: 10.3987/R-1981-11-1963
Photochemical Reaction of 2-Bromo-3-methoxy-1,4-naphthoquinone with Sily Enol Ether — One-pot Synthesis of Polycyclic Aromatic Compounds

Kazuhiro Maruyama,* Seiji Tai, Masahiro Tojo, and Tetsuo Otsuki

*Department of Chemistry, Faculty of Science, Kyoto University, Sakyo, Kyoto 606-8502, Japan

Abstract

5-Hydroxybenz[a]anthracene, 2-aryl-2,6-dihydroxy-5-fomyl-2,3-dihydronaphtho[1,2-b][1,4]dioxin, and 4-arylnaphtho[2,3-d][1,3]dioxepin derivatives were synthesized by one-pot photochemical reaction of 2-bromo-3-methoxy-1,4-naphthoquinone with trialkylsilylenolether.