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■ Chemistry of Acronycine V. Unexpected Reactivity of Dihydronoracronycine

Shinji Funayama and Geoffrey A. Cordell

*Program for Collaborative Research in the Pharmaceutical Sciences, College of Pharmacy, University of Illinois at Chicago, 833 South Wood St., Chicago, IL 60612-7231, U.S.A.

Abstract

Dihydronoracronycine (6) undergoes a condensation-disproportionation reaction in methanolic hydrochloric acid with the dimers of noracronycine 2 and 4 which leads to their corresponding dihydro derivatives 8 and 9, and to the trimers 5 and 7, respectively.