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Communication | Regular issue | Vol 22, No. 3, 1984, pp.453-456
Published online, 1st January, 1970
DOI: 10.3987/R-1984-03-0453
Synthesis of the C-11 Oxygenated Erythrina Alkaloids

Maria Helena Sarragiotto, Paulo A. da Costa, and Anita J. Marsaioli*

*Instituto de Química, Universidade Estadual de Campinas (UNICAMP), Caixa Postal 6154, CEP 13083-970, Campinas, Sao Paulo, Brazil

Abstract

Introduction of an oxygenated function at C-11 of the Erythrina alkaloid skeleton was obtained by treating erysovine with lead tetraacetate. Unfortunately simultaneous substitution of the C-3 OMe by -OAc has occurred and modifications as changing the reaction conditions and/or the phenolic compound to erysodine did not lead to successful results.