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Communication | Regular issue | Vol 22, No. 4, 1984, pp.721-724
Published online, 1st January, 1970■ Photo-sensitized Oxygenation of Monocyclic 1H-1,3-Diazepines
Published online, 1st January, 1970
DOI: 10.3987/R-1984-04-0721
■ Photo-sensitized Oxygenation of Monocyclic 1H-1,3-Diazepines
Jyoji Kurita, Hirokazu Kojima, and Takashi Tsuchiya*
*School of Pharmacy, Hokuriku University, 3-Ho, Kanagawa machi, Kanazawa 920-1181, Japan
Abstract
The sensitized photooxygenation of monocyclic 1H-1,3-diazepines (1a-c) affords fragment products (2) to (7), which may be derived from the corresponding 4,7-endoperoxides (8) or the 4,5-dioxetanes (9) initially formed. The other possible dioxides and their decomposition products are not detected.
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