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Communication | Regular issue | Vol 22, No. 5, 1984, pp.987-991
Published online, 1st January, 1970
DOI: 10.3987/R-1984-05-0987
Synthesis of 2-(4,5-Dihydrofuryl)- and 2-(Tetrahydrofuryl)dimethylhydrosilanes. Rearrangement of 2-(Tetrahydrofuryl)dimethylhydrosilane with Ring Expansion

Edmunds Lukevics,* Vladimir Gevorgyan, Yuri Goldberg, Juris Popelis, Maris Gavars, Alexaneder Gaukhman, and Mariya Shimanska

*Institute of Organic Synthesis, Academy of Science of the Latvian SSR, 21 Aizkraukels, Riga-6, Latvia, Latvia


2-(4,5-Dihydrofuryl)- and 2-(tetrahydrofuryl)dimethylhydrosilanes (I and II) have been synthesized. The latter rearranges easily and quantitatively to 1-oxa-2-sila-2,2-dimethylcyclohexane in the presence of palladium catalyst. The possibility of hydrosilylation of alkenes and alkynes by I and II has been demonstrated.