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Report | Regular issue | Vol 23, No. 12, 1985, pp.3085-3094
Published online, 1st January, 1970
DOI: 10.3987/R-1985-12-3085
Transformation from Aporphine X-Oxides to 1-(N-Methyl-N-hydroxylaminoethyl)phenanthrene Derivatives

Sheng-Teh Lu* and Yang-Chang Wu

*School of Pharmacy, Kaohsiung Medical College, 100 Shih Chuen 1st Rd., Kaohsiung 80708, Taiwan, R.O.C.

Abstract

Neat treatment of aporphine N-oxides prepared by the m-chloroperbenzoic acid (m-CPBA) oxidation of aporphines afforded 1-(N-methyl-N-hydroxylaminoethyl)phenanthrene derivatives which were characterized by the physical and chemical evidences. The biogenetic pathway from aporphines to phenanthrenes is also discussed.