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Paper | Regular issue | Vol 24, No. 1, 1986, pp.69-75
Published online, 1st January, 1970
DOI: 10.3987/R-1986-01-0069
Nitrogen Brodgehead Compounds. Part 58. Nucleophilic Ring Cleavage of 1-Thia-2a,5a-diazaacenaphthene Ring

István Bitter,* Gábor Tóth, Béla Pete, István Hermecz, Kálmán Simon, and Zoltán Mészáros

*Department of Organic Chemical Technology, Technical University of Budapest, H-1521 Budapest, Gellért tér 4, Hungary


1-Thia-2a,5a-diazaacenaphtene ring is cleaved by amines affording thiazolo[4,5-b]pyridine derivatives which undergo degenerate ring transformation.