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Report | Regular issue | Vol 24, No. 5, 1986, pp.1275-1277
Published online, 1st January, 1970
DOI: 10.3987/R-1986-05-1275
The Structure of Heterophylloidine and Panicutine

S. William Pelletier,* Balawant S. Joshi, Haridutt K. Desai, Al Panu, and Alfred Katz

*Department of Chemistry, Institute for Natural Products Research, The University of Georgia, Chemistry Building, Athens, Georgia 30602-2556, U.S.A.

Abstract

Heterophylloidine (Aconitum heterophylloides Stapf) and panicutine (A. paniculatum Lam.) have been shown to be identical. CD measurements on derivatives of heterophylloidine and hetisine indicate that the keto groups in panicutine must be located at C(6), C(13) and not at C(6), C(11) as previously reported. The structure of panicutine is therefore 1, as proposed earlier for heterophylloidine.