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Yoshito Kishi (1937-2023)
Yoshito Kishi (1937-2023)
Professor. Yoshito Kishi,
a member of the Honorary Editorial Associates of HETEROCYCLES,
has passed away on January 9, 2023 at the age of 85.
I deeply express my regret over his death.
Kunio Ogasawara
Editor
January 13, 2023
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Paper | Regular issue | Vol 24, No. 8, 1986, pp.2239-2245
Published online, 1st January, 1970■ Unusual Rearrangement Reaction of Quebrachamine Derivative Catalyzed by Cyanide Anion
Published online, 1st January, 1970
DOI: 10.3987/R-1986-08-2239
■ Unusual Rearrangement Reaction of Quebrachamine Derivative Catalyzed by Cyanide Anion
Kiyoshi Yoshida, Sumihiro Nomura, Yoshihiko Nishibata, and Yoshio Ban*
*Faculty of Pharmaceutical Sciences, Toho University, 2-2-1, Miyama, Funabashi, Chiba 274-8510, Japan
Abstract
Cyanation of trimethylammonium salt 8 with potassium cyanide afforded 3-cyano derivatives 9a and 9b accompanied by a significant amount of unexpected rearrangement product 10. The structure of 10 was established by single X-ray crystallographic analysis.
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