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Communication | Regular issue | Vol 24, No. 11, 1986, pp.3019-3022
Published online, 1st January, 1970
DOI: 10.3987/R-1986-11-3019
A Convenient Preparation of Sulfinic Acids by the Reaction of 2-Sulfonylpyridines and Their N-Oxides with Nucleophiles

Naomichi Furukawa,* Masayuki Tsuruoka, and Hisashi Fujihara

*Department of Chemistry, University of Tsukuba, 1-1-1 Ten-nodai, Tsukuba-shi, Ibaraki, 305-8571, Japan

Abstract

Ipso-substitution reaction of 2-sulfonylpyridines and their N-oxides with alkoxide or thiolate anion afforded the sodium salts of sulfinic acids together with the corresponding substitution products in high yields. This procedure becomes a convenient and versatile method for preparation of various sulfinic acids.