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Paper | Regular issue | Vol 24, No. 11, 1986, pp.3097-3104
Published online, 1st January, 1970
DOI: 10.3987/R-1986-11-3097
Carbene versus Dimer Formation from Diazo Derivatives: The Anomalous Behaviour of 2-Diazothiazolines

Josep Castells,* Francisco López Calahorra, and Fernando Geijo

*Departmento de Química Orgánica, Instituto Químico de Sarriá, Universitat de Barcelona, 08028 Barcelona, Spain

Abstract

Different oxidation procedures of 2-thiazolinone hydrazones, the anomalous behaviour of the resulting 2-diazothiazolines and a quantum-theoretical interpretation based in MNDO calculations are reported.