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Paper | Regular issue | Vol 26, No. 3, 1987, pp.763-766
Published online, 1st January, 1970
DOI: 10.3987/R-1987-03-0763
Hydrogenation and Hydrosilylation of Quinoxaline by Homogeneous Rhodium Catalysts

Shizuaki Murata, Takashi Sugimoto, and Sadao Matsuura

*Graduate School of Environmental Studies, Nagoya University, Chikusa, Nagoya, Aichi 464-8601, Japan


Hydrogenation of quinoxalines by a homogeneous rhodium catalyst gives tetrahydroquinoxalines. The catalytic process is applicable for hydrosilylation of quinoxalines. 2-Methylquinoxaline is asymmetrically hydrosilylated by a chiral catalyst.