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Zenichi Yoshida (1925-2023)
Zenichi Yoshida (1925-2023)
Professor. Zenichi Yoshida,
a member of the Honorary Advisors of HETEROCYCLES (1975-1998),
has passed away on May 4, 2023 at the age of 97.
I deeply express my regret over his death.
Kunio Ogasawara
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May 11, 2023
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Communication | Regular issue | Vol 26, No. 9, 1987, pp.2351-2354
Published online, 1st January, 1970■ Oxonitine Revisited: Its Mechanism of Formation from Aconitine
Published online, 1st January, 1970
DOI: 10.3987/R-1987-09-2351
■ Oxonitine Revisited: Its Mechanism of Formation from Aconitine
Palaniappan Kulanthaivel and S. William Pelletier
*Department of Chemistry, Institute for Natural Products Research, The University of Georgia, Chemistry Building, Athens, Georgia 30602-2556, U.S.A.
Abstract
Oxidation of aconitine (2) to oxonitine (1) with KMnO4 proceeds by three mechanisms, involving the CH3 and CH2 carbons of the N-ethyl group and the carbon of the solvent as sources of the N-CHO group of oxonitine.
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