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Paper | Regular issue | Vol 26, No. 9, 1987, pp.2455-2460
Published online, 1st January, 1970
DOI: 10.3987/R-1987-09-2455
Rearrangement of a Substituted Epoxytetrahydropyran to the Corresponding Tetrahydrofurancarbaldehyde

Urs Séquin and Andreas Schneider

*Institut für Organische Chemie, Universitat Basel, St. Johanns-Ring 19, CH-4056 Basel, Switzerland


The aluminum chloride catalyzed reaction of a substituted 3,4-epoxytetrahydropyran with N,N-dimethyl-trimethylsilylamine did not lead to the expected silylated β-aminoalcohol but rather to a tetrahydrofurancarbaldehyde.