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Yoshito Kishi (1937-2023)
Yoshito Kishi (1937-2023)
Professor. Yoshito Kishi,
a member of the Honorary Editorial Associates of HETEROCYCLES,
has passed away on January 9, 2023 at the age of 85.
I deeply express my regret over his death.
Kunio Ogasawara
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January 13, 2023
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Communication | Regular issue | Vol 26, No. 11, 1987, pp.2861-2864
Published online, 1st January, 1970■ Thermal Rearrangements of 8-Aza- and 8-Oxa-3,4-diazatricyclo-[5.1.0.02.6]oct-4-enes
Published online, 1st January, 1970
DOI: 10.3987/R-1987-11-2861
■ Thermal Rearrangements of 8-Aza- and 8-Oxa-3,4-diazatricyclo-[5.1.0.02.6]oct-4-enes
Jyoji Kurita, Hiroichi Sakai, and Takashi Tsuchiya
*School of Pharmacy, Hokuriku University, 3-Ho, Kanagawa machi, Kanazawa 920-1181, Japan
Abstract
Flash vacuum pyrolysis of the 8-oxa-3,4-diazatricyclo-[5.1.0.02,6]oct-4-enes (7) resulted in rearrangement to give the - 1-amino-2-formylpyrroles (7), presumably via the 1,4,5-oxadiazocines (14)whereas that of the 8-aza analogues (8) gave the 3a,6a-dihydropyrrolo[2,3-clpyrazoles (12) by a different type of rearrangement.
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