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Paper | Regular issue | Vol 26, No. 12, 1987, pp.3197-3202
Published online, 1st January, 1970
DOI: 10.3987/R-1987-12-3197
The [3+2] Cycloaddition Reaction of Nonstabilized Azomethine Ylide Generated from Trimetylmine N-Oxide to C=C, C=N, and C=S Bonds

René Beugelmans, Jacqueline Chastanet, and Georges Roussi

*Institut des Chimie des Substances Naturelles, C.N.R.S., 1 avenue de la Terrasse, Bat. 27, 91198 Gif-sur-Yvette Cedex, France

Abstract

The reported cycloaddition reactions between nonstabilized azomethine ylide Y generated from trimethylamine N-oxide 1 and unactivated C≡C 2 - 4, C=N 5 and C=S 6, 7 bonds constitute an attractive entry respectively to pyrrolines and pyrroles 10 - 13, imidazalidine 14 and thiazolidines 15, 16.