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Review | Regular issue | Vol 27, No. 5, 1988, pp.1253-1268
Published online, 1st January, 1970
DOI: 10.3987/REV-87-379
New Diels-Alder Reactions with Vinylindoles: A Regio- and Stereocontrolled Access to Annellated Indoles and Derivatives

Ulf Pindur*

*Department of Chemistry and Pharmacy, Institute of Pharmacy, University of Mainz, Saarstrasse 21, D-55122 Mainz, Germany

Abstract

New structural aspects of vinylindoles for predicting the outcome of Diels-Alder reactions are presented for the first time. Novel, mostly regio- and stereoselective cycloaddition reactions with 3- and 2-vinylindoles are described briefly and, in some cases, new applications for the syntheses of alkaloids are discussed.