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Communication | Special issue | Vol 7, No. 2, 1977, pp.787-792
Published online, 1st January, 1970
DOI: 10.3987/S-1977-02-0787
Chiroptical Properties of Fluorescamine Condensation Compounds with Chiral Secondary Amines in situ

Voldemar Toome,* Bodge Wegrzynski, and June Dell

*The Department of Chemistry Research, Hoffman-La Roghe Inc., Nutley, New Jersey 07110, U.S.A.

Abstract

Chiral secondary amines react readily with fluorescamine (FLURAM®) to form aminoenone-type chromophores with long wavelength absorption maxima at 300-320 nm. The chiroptical properties of the reaction mixtures reflect the absolute configuration of secondary amines in situ.