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Communication | Special issue | Vol 25, No. 1, 1987, pp.51-53
Published online, 1st January, 1970
DOI: 10.3987/S-1987-01-0051
An Aromatic Version of Claisen Rearangement of Lactonic Silyl Enolates — A New Access to Potential Intermediates for Eudesmane Type of Sesquiterpenes

Hideo Nemoto, Eiki Shitara, Keiichiro Fukumoto, and Tetsuji Kametani

*Pharmaceutical Institute, Tohoku University, Aobayama, Sendai 980-8578, Japan

Abstract

A new stereoselective synthesis of suitably substituted furanodecalins (9) ~ (12) via the Claisen rearrangement of furfuryl lactonic silyl enolate (6) derived from the furfuryl lactone (4) is described.