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Communication | Special issue | Vol 79, No. 1, 2009, pp.417-422
Published online, 2nd December, 2008
DOI: 10.3987/COM-08-S(D)55
Stereoselective Synthesis of 2,3,5-Trisubstituted Pyrrolidines Using Metathesis-Derived β-Aminoallylsilanes

Alison D. McElhinney and Stephen P. Marsden*

*School of Chemistry, The University of Leeds, Leeds, LS2 9JT, U.K.


Amine-functionalised allylsilanes, readily prepared by olefin cross metathesis of protected homoallylamines with allyltrimethylsilane, undergo stereoselective condensation with aldehydes to yield trisubstituted pyrrolidines.