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Paper | Special issue | Vol 79, No. 1, 2009, pp.1019-1024
Published online, 8th January, 2009
DOI: 10.3987/COM-08-S(D)79
An Energy Transfer Chemiluminescent Reaction of Lophine Peroxides

Masaru Kimura,* Kaoru Akaki, Yasunobu Mishima, Hiroyuki Araki, and Takeshi Fukai

*No. 185, Qianshan Middle Road, Hi-Tech Zone, Anshan, Liaoning, China

Abstract

A linear correlation existed between the absorption energy of activators (Eo-o's) and the sensitized chemiluminescence (CL) yields (φSCL's) for the CL reaction of lophine peroxides (2a and 2b), whereas a linear correlation did not exist between their oxidation potentials (Eox's) and φSCL's. Based on the finding, an energy transfer mechanism is likely rather than an electron transfer mechanism like the CIEEL mechanism.