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Note | Regular issue | Vol 78, No. 5, 2009, pp.1317-1324
Published online, 26th January, 2009
DOI: 10.3987/COM-08-11632
Studies on the Synthesis and Crystal Structure of N-(1-Naphthyl)succinimide

Ying Wang, Hailong Yang, Hexian Li, and Guochang Wang*

*Institute of Polymer Chemistry, Nankai University, 94 Weijin Road, Tianjin, 300071, China

Abstract

A modified two-step procedure for synthesis of N-(1-naphthyl)succinimide (NaS) was developed, and its single crystal was prepared for the first time. The molecular and crystal structures were characterized by XRD, FT-IR, 1H NMR, DSC, etc. It has been found that the melting point (159-160.5 °C) of our product is ca 10 °C higher than the documented values, while the characteristic infrared absorption band of carbonyl group splits into two peaks (1705cm-1/1779cm-1) rather than one as reported in the references. These discrepancies were further examined by X-ray crystallographic analysis. Meanwhile, photophysical spectroscopy was found to be powerful to study the molecular structure and crystal morphology of organic compound.