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Paper | Regular issue | Vol 83, No. 2, 2011, pp.299-309
Published online, 27th December, 2010
DOI: 10.3987/COM-10-12081
The Synthesis of Novel Palladium(II) Carbene Complexes, Azolium Salts and Their Catalytic Properties

Beyhan Yiğit, Murat Yiğit,* İsmail Özdemir, and Engin Çetinkaya

*Department of Chemistry, Faculty of Arts and Sciences, Adıyaman University, 20240 Adıyaman , Turkey

Abstract

Novel three 1,3-bis[2-(N,N’-diisopropylamino)ethyl]imidazolinium, 1,3-bis[2-(N,N’-diisopropylamino)ethyl]benzimidazolium and 1-(2-diisopropyl- aminoethyl)-3-(2-methoxyethyl)benzimidazolium chloride salts (1, 3a-b) and two palladium complex (2, 4) have been prepared and characterized by C, H, N analysis, 1H NMR and 13C NMR and they have been investigated their catalytic activity in the Heck and Suzuki coupling reactions.