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Short Paper | Special issue | Vol 84, No. 2, 2012, pp.1271-1276
Published online, 15th July, 2011
DOI: 10.3987/COM-11-S(P)36
2nd Generation Palladium-Catalyzed Cycloalkenylation in Iridoid Synthesis: Diastereoselective Total Synthesis of Isoiridomyrmecin and Isodihydronepetalactone

Kazutaka Takeda and Masahiro Toyota*

*Department of Chemistry, Graduate School of Science, Osaka Prefecture University, Sakai, Osaka 593-8531, Japan


Two different types of iridoids, isoiridomyrmecin and isodihydronepetalactone, were diastereoselectively synthesized using a 2nd generation palladium-catalyzed cycloalkenylation as the key step.