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Review | Regular issue | Vol 85, No. 4, 2012, pp.799-819
Published online, 20th February, 2012
DOI: 10.3987/REV-12-728
Cyclic Triolborate Salts: Novel Reagent for Organic Synthesis

Yasunori Yamamoto*

*Division of Chemical Process Engineering, Graduate School of Engineering, Hokkaido University, Kita 13 Nishi 8, Kita-ku, Sapporo, Hokkaido 060-8628, Japan

Abstract

This review summarizes metal-catalyzed C-C and C-N bond-forming reactions using novel heteroaryltriolborate salts for palladium- or copper-catalyzed cross-coupling reactions with arylhalides or amines and for rhodium-catalyzed addition reactions to α,β-unsaturated carbonyl compounds or imines.