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Paper | Special issue | Vol 88, No. 1, 2014, pp.213-221
Published online, 28th March, 2013
DOI: 10.3987/COM-13-S(S)1
Introduction of Heteroarene Functionality on the Bipedal-Thiol-Capped Gold Nanoparticle by Deprotonative C-H Coupling with Palladium Complex

Atsushi Sugie, Hiroki Yamauchi, Kei Miyamura, Kenta Kumazawa, Shota Tanaka, Kiyoshi Kanie, Atsushi Muramatsu, and Atsunori Mori*

*Chemical Science & Technology, Graduate School of Engineering, Kobe University, 1-1 Rokkodai-cho, Nada-ku, Kobe 657-8501, Japan

Abstract

Gold nanoparticle stabilized by adsorption of bipedal thiol whose end is modified with bromoarene is prepared to undergo palladium-mediated deprotonative C-H arylation reaction. Heteroarenes are introduced onto the organic moiety of the nanoparticle.