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Review | Regular issue | Vol 87, No. 8, 2013, pp.1625-1658
Published online, 24th June, 2013
DOI: 10.3987/REV-13-773
Recent Advances in the Syntheses of Decalin Type Natural Products

Hiroyuki Akita*

*Department of Pharmaceutical Sciences, Nihon Pharmaceutical University, 10281 Komuro, Ina-machi, Kitaadachi-gun, Saitama, 362-0806, Japan

Abstract

This review summarizes the practical synthesis of both enantiomers of chiral intermediate for the syntheses of the natural products possessing the bicyclo[4.4.0]ring system with 4,4,10-trimethyl groups and their application to the total syntheses of the related natural products. Chiral induction was carried out based on enzymatic resolution or optical resolution using chiral auxiliary.