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Short Paper | Special issue | Vol 88, No. 2, 2014, pp.1615-1624
Published online, 27th September, 2013
DOI: 10.3987/COM-13-S(S)114
Palladium-Catalyzed Cross-Coupling Reaction of Trialkylbismuthines with 2-Haloazines and Diazines

Pauline Petiot and Alexandre Gagnon*

*Département de chimie, UQAM - Université du Québec à Montréal, C.P. 8888, Succ. Centre-Ville, Montréal, Québec, H3C 3P8, Canada


An efficient method for the cross-coupling reaction of primary trialkybismuth reagents with 2-haloazines and diazines is reported. The reaction functions with pyridines, pyrimidines, pyridazines and pyrazines and tolerates many functional groups. This method gives access to 2-alkylazines and diazines, a class of compounds which is important in medicinal chemistry.