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Paper | Regular issue | Vol 87, No. 10, 2013, pp.2031-2036
Published online, 13th September, 2013
DOI: 10.3987/COM-13-12800
INTENTIONAL SYNTHESIS OF BINARY RADICAL THAT BEARING NITRONYL AND IMINO NITROXIDES: X-RAY ANALYSIS AND MAGNETIC MEASUREMENT

Fumiyasu Iwahori,* Takayuki Suzuki, and Kosuke Kato

*Department of Chemistry, College of Humanities and Sciences, Nihon University, Sakurajousui, Setagaya-Ku, Tokyo 156-8550, Japan

Abstract

We have synthesized new binary radical that bearing both nitronyl and imino nitroxides with the aim of enabling to control the occupancy of oxygen atom in the nitronyl nitroxide crystal. X-ray analysis, ESR study and magnetic measurement revealed that the tuning of occupancy of the oxygen atom in the crystal might make an effect on the magnetic property of nitronyl nitroxides.