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Short Paper | Regular issue | Vol 87, No. 11, 2013, pp.2395-2402
Published online, 16th October, 2013
DOI: 10.3987/COM-13-12845
Allylation of N,N-Acetal Derivatives Using Allyl Tin Regent in the Presence of Aluminum Chloride

Xiaonan Sun, Takanori Obu, Tatsuro Kijima, Satoshi Murakami, Shigeru Matsuba, Miho Kusakari, and Bunpei Hatano*

*Graduate School of Science and Engineering, Yamagata University, 3-16 Jonan 4-Chome, Yonezawa 992-8510, Japan

Abstract

Allylation of N,N-acetal derivatives proceeded efficiently using allyl tin regent in the presence of aluminum chloride, giving homoallylamines in good yields. This allylation was applied for N,S-acetals to give the corresponding homoallylamines.