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Short Paper | Regular issue | Vol 89, No. 2, 2014, pp.487-493
Published online, 25th December, 2013
DOI: 10.3987/COM-13-12895
Facile Synthesis of Glycidates via Oxidation of Acrylates with Aqueous Solution of NaOCl in the Presence of Ammonium Salts

Bungo Ochiai* and Taiki Hirano

*Faculty of Engineering, Department of Chemistry and Chemical Enginnering, Yamagata University, 3-16 Jonan 4-Chome, Yonezawa 992-8510, Japan

Abstract

Various glycidates were obtained in high yields via green oxidation of acrylates with aqueous solution of NaOCl in the presence of ammonium salts. The appropriate choice of ammonium salts fitting to the polarity of the substrates and the reaction under slightly basic conditions were essential for efficient reactions.