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Communication | Regular issue | Vol 89, No. 4, 2014, pp.963-969
Published online, 4th March, 2014
DOI: 10.3987/COM-14-12957
Sequential Radical Addition and Fischer-Type Indolization Reactions of Conjugated Hydrazones for the Preparation of α-Alkylindole-3-acetic Acids

Yuta Ito, Masafumi Ueda,* Naomi Matsuda, Yuika Nishida, and Okiko Miyata*

*Department of Medicinal Chemistry, Kobe Pharmaceutical University, 4-19-1, Motoyamakitamachi, Higashinada, Kobe 658-8558, Japan


A domino reaction, consisting of sequential regioselective radical addition and Fischer-type indolization reactions, has been developed for the construction of α-alkylindole-3-acetates from conjugated hydrazones.