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Short Paper | Special issue | Vol 95, No. 2, 2017, pp.1245-1253
Published online, 15th February, 2017
DOI: 10.3987/COM-16-S(S)80
A Fischer Indolization Strategy toward the Total Synthesis of (–)-Goniomitine

Beau P. Pritchett, Jun Kikuchi, Yoshitaka Numajiri, and Brian M. Stoltz*

*The Warren and Katharine Schlinger Laboratory for Chemistry and Chemical Engineering, Division of Chemistry and Chemical Engineering, California Institute of Technology, 1200 East California Blvd. MC101-20, Pasadena, CA 91125, U.S.A.

Abstract

A Fischer indolization strategy toward the core of (–)-goniomitine is reported. Initial investigations into the Pd-catalyzed asymmetric allylic alkylation of dihydropyrido[1,2-a]indolone (DHPI) substrates are also discussed.