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Short Paper | Regular issue | Vol 94, No. 11, 2017, pp.2111-2124
Published online, 5th October, 2017
DOI: 10.3987/COM-17-13804
Synthesis of a Type of Bridged Heterocycles via Tetraynes

Xiangzhen Meng, Dong Cheng,* Shuang Lv, Jie Ma, and Yimin Hu*

*Laboratory of Functional Molecular Solids, Ministry of Education Anhui Key Laboratory of Functional Molecular-Based Materials, Institute of Organic Chemistry, School of Chemistry and Materials Science, Anhui Normal University Wuhu Anhui, China
*Institute of Chemical and Materials Engineering, Chaohu University, Chaohu Anhui, China


A simple method has been developed for the synthesis of a type of bridged heterocycles using tetraynes. The strategy uses 1,3-diphenylisobenzofuran or 2,5-diphenylfuran and tetraynes as substrates and reactions proceed through an HDDA–[4+2] adduct. Products are obtained in moderate to good yield.