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Paper | Special issue | Vol 97, No. 2, 2018, pp.931-945
Published online, 12th April, 2018
DOI: 10.3987/COM-18-S(T)72
Arylation Reactions of Monocarba-closo-Dodecaborate at the Boron Vertices

Mai Otsuka, Gaku Akimoto, Atsuya Muranaka, Ryo Takita,* and Masanobu Uchiyama*

*Graduate School of Pharmaceutical Sciences, The University of Tokyo, 7-3-1 Hongo, Bunkyo-ku, Tokyo 113-0033, Japan

Abstract

We have developed two methods for aryl group introduction at the boron vertices of monocarba-closo-dodecaborate under palladium catalysis. Details of reaction development, as well as mechanistic insights, are described.