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Obituary
Yoshito Kishi (1937-2023)
Yoshito Kishi (1937-2023)
Professor. Yoshito Kishi,
a member of the Honorary Editorial Associates of HETEROCYCLES,
has passed away on January 9, 2023 at the age of 85.
I deeply express my regret over his death.
Kunio Ogasawara
Editor
January 13, 2023
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Communication | Regular issue | Vol 94, No. 12, 2017, pp.2222-2228
Published online, 10th November, 2017
Published online, 10th November, 2017
DOI: 10.3987/COM-17-13824
■ Direct β-Arylation of Furans with Aryl Iodides Catalyzed by Dinuclear Palladium Complexes
Takahiro Goto, Hayate Kato, and Naofumi Tsukada*
*Department of Chemistry, Faculty of Science, Shizuoka University, 836 Ohya, Shizuoka 422-8529, Japan
Abstract
Dinuclear palladium complexes formed by a chelate-bridging ligand showed β-selectivity in the direct arylation of furans with iodoarenes. In contrast, the arylation using PPh3 or bpy as ligands gave α-arylfurans as major products. The arylation can be applied to several furans bearing functional groups except electron-withdrawing groups.
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