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Paper | Special issue | Vol 99, No. 2, 2019, pp.1276-1303
Published online, 14th February, 2019
DOI: 10.3987/COM-18-S(F)100
Preparation of Tricyclic Analog as CDE Ring Model of Renieramycin Marine Natural Product by Novel Photo-Induced Transformation of 6-Methoxy-1,2,3,4-tetrahydroisoquinoline-5,8-dione

Masashi Yokoya, Shohei Takahashi, and Naoki Saito*

*Graduate School of Pharmaceutical Sciences, Meiji Pharmaceutical University, 2-522-1 Noshio, Kiyose, Tokyo, 204-8588, Japan


2-Acetyl-6-[(benzyloxy)methyl]-9-methoxy-8-methyl-11,11a- dihydro-2H-pyrazino[1,2-b]isoquinoline-1,4,7,10(3H,6H)-tetraone (11a) was prepared as the CDE ring model of renieramycins, and its novel photo-induced transformation was demonstrated to construct a 1,3-dioxol ring.