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Short Paper | Special issue | Vol 99, No. 1, 2019, pp.703-715
Published online, 16th October, 2018
DOI: 10.3987/COM-18-S(F)39
Nucleophilic Addition to N-Benzoylisoquinolinium Cation Catalyzed by Sodium Tetracyanocyclopentadienides

Takeo Sakai,* Mai Hattori, Akari Tada, Junpei Matsuoka, and Yuji Mori

*Faculty of Pharmacy, Meijo University, 150 Yagotoyama, Tempaku-ku, Nagoya 468-8503, Japan

Abstract

Tetracyanocyclopentadienide-catalyzed nucleophilic addition to an N-benzoylisoquinolinium cation is reported. The reaction is accelerated by the in situ formation of the soluble lipophilic salt of an N-benzoylisoquinolinium cation and a tetracyanocyclopentadienide anion.