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Communication | Regular issue | Vol 98, No. 10, 2019, pp.1345-1353
Published online, 25th October, 2019
DOI: 10.3987/COM-19-14163
Interaction of the Dihydropyridine/Pyridinium Redox Pair Fixed into a V-Shaped Conformation

Yasukazu Hirao,* Mitsuru Teraoka, and Takashi Kubo*

*Department of Chemistry, Graduate School of Science, Osaka University, 1-1 Machikaneyama, Toyonaka, Osaka 560-0043, Japan

Abstract

A new V-shaped molecule incorporating a dihydropyridine and a pyridinium moiety was synthesized and evaluated for its effect on the interaction between the hydride donor-acceptor pair. Spectroscopic, electrochemical, and computational studies have revealed the presence of the charge transfer interaction as a consequence of the electron donor-acceptor association.