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Short Paper | Regular issue | Vol 106, No. 4, 2023, pp.695-706
Published online, 24th February, 2023
DOI: 10.3987/COM-23-14810
■ Synthesis of 2-Aryloxy-2,4,4,6,6-pentachlorocyclotriphosphazenes (N3P3Cl5(OAr)): Monoaryloxylatioin of Hexachlorocyclotriphosphazene (N3P3Cl6) and Mass Spectra of Chlorocyclotriphosphazene Derivatives. Difference between EI vs. ESI Methods

Manabu Kuroboshi,* Ryota Takahashi, and Hideo Tanaka

*Tsushima-naka 3-1-1, Kita-ku, Okayama, Okayama, Japan

Abstract

Hexachlorocyclotriphosphazene (HCCP, N3P3Cl6) was treated with Li aryloxide in THF at -40 ºC to give monoaryloxypentachlorocyclotriphosphazene (N3P3Cl5(ArO)) selectively. N3P3Cl5(ArO) did not give further aryloxylated products N3P3Cl6-n(ArO)n (n ≥ 2) under the same reaction conditions. In mass spectra (MS) of N3P3Cl5(ArO), [N3P3Cl5(ArO)]+ were detected by EI method, whereas partially hydrated products [N3P3Cl4(ArO)(O-)] were detected instead of [N3P3Cl5(ArO)]+ by ESI method.